Anmol Chemicals is the pioneer manufacturers of Ethyl chloroacetate, Pharmaceutical Excipients Fragrance & Flavor chemicals in India. We offer Halal and Kosher Ethyl chloroacetate made in an ISO9001:2008, ISO22000:2005 (FSSC22000) and cGMP certified facility. Our group has several manufacturing facilities spread across the world, supported by toll manufacturers and representatives in UAE, Europe, Africa, USA, China and has several associated manufacturing facilities spread across India. All the Information on Physics, Chemistry, Applications, Uses and Technology on Manufacture of Ethyl chloroacetate is in these pages.
The units have one or more of the certifications like FDA GMP, ISO 9001, ISO 22000, HACCP, REACH, Kosher & Halal

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Ethyl Chloroacetate Manufacturers SDS GHS, MSDS Sheet

Arabic إيثيل تشلورواسيتاتي مصنعين
German Chloro Ethylacetat, Chloroacetate Hersteller
Dutch Chloro ethylacetaat, Chloroacetate fabrikanten
Italian Cloroacetato di etile, acetato di cloro, produttori
Spanish Cloro acetato de etilo, fabricantes de Chloroacetate
French AcÚtate d'Úthyle Chloro, fabricants de Chloroacetate
Portuguese Cloroacetato de etila, acetato de cloro, fabricantes

MSDS of Ethyl Chloroacetate Manufacturers

Ethyl Chloroacetate SDS GHS, Material Safety Data Sheet

1. Product Identification

Synonyms: Chloroacetic Acid, ethyl ester; Ethyl alpha-chloroacetate; Ethyl chloroethanoate; Ethyl monochloracetate; Ethyl monochloroacetate
CAS No.: 105-39-5
EINECS EC No.: 203-294-0
Molecular Formula: ClCH2CO2C2H5
Molecular Weight: 122.55
Recommended usage: Industrial Manufacturing.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)
:

Flammable liquids (Category 3) H226
Acute toxicity, Oral (Category 3) H301
Acute toxicity, Inhalation (Category 3) H331
Acute toxicity, Dermal (Category 3) H311
Serious eye damage (Category 1) H318
Acute aquatic toxicity (Category 1) H400

Labelling according Regulation (EC) No 1272/2008

GHS Label Elements
Toxic
Toxic
GHS Label Elements
Flammable
Flammable
GHS Label Elements
Corrosive
Corrosive
GHS Label Elements
Marine
Marine Pollutant

Signal Words: Danger

Hazard statements:
H226: Flammable liquid and vapor.
H301: Toxic if swallowed.
H311: Toxic in contact with skin.
H318: Causes serious eye damage.
H331: Toxic if inhaled.
H400: Very toxic to aquatic life.

Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P330: Rinse mouth.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+352: IF ON SKIN: Wash with soap and water.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P370+378: In case of fire: Use water spray or fog for extinction.
P403+233+235: Store in a well ventilated place. Keep container tightly closed. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to authorized agents only.

According to European Directive 67/548/EEC as amended.
Hazard symbol(s): T N
R-phrase(s):
R 10 Flammable.
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R50 Very toxic to aquatic organisms.
S-phrase(s):
S45 In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
S 7/9 Keep container tightly closed and in a well-ventilated place.
S61 Avoid release to the environment. Refer to special instructions/ Safety
data sheets.

OSHA Hazards: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
HMIS (Perceived): Health hazard: 2, Flammability: 2, Reactivity: 0, Personal Protection: H
NFPA (Perceived): Health hazard: 2, Fire: 2, Reactivity Hazard: 0, Protective Equip: Goggles, Lab Coat. Vapor respirator

2. Composition/Information on Ingredients

Ingredient: Ethyl Chloroacetate
CAS No.: 105-39-5
Percent: 97 - 100%

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Flammability of the Product: Flammable.
Auto-Ignition Temperature: 452C.
Flash Points: 53C
Flammable Limits: Not available.
Products of Combustion: Carbon dioxide, Carbon monoxide, fumes & Hydrochloric Acid.
Fire: Inflammable.
Explosion: Explosive in presence of heat.
Fire Extinguishing Media: Use water spray or fog. Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. Never direct a water jet in the container in order to prevent any splashing of the product which could cause spreading of the fire. Cool containing vessels with water jet in order to prevent pressure build-up, auto-ignition or explosion.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes.

6. Accidental Release Measures

Small Spill: Avoid mist formation. Avoid breathing mist. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Remove all sources of ignition. Provide proper ventilation. If liquid - absorb the material on a porous, inert material such as earth, sand or vermiculite. If solid/powder - carefully sweep up the material without causing dust. Dispose of in accordance with local regulations.

Large liquid spillages should be contained by use of sand or another inert material. The spillage should be transferred to a suitable container and recovered or disposed of in accordance with local regulations. Because of the danger of spontaneous combustion, any combustible material, such as cloth, used for cleaning spillages, should be saturated with water and disposed of promptly, preferably by incineration.

7. Handling and Storage

Do not ingest. Do not breathe dust or mist. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep Ethyl Chloroacetate in a tightly closed container, stored in a cool, dry, ventilated area. Keep the product in its original container well sealed,in a dry and ventilated area,away from potential sources of ignition and protected from light. Protect against physical damage.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: Not Established.
Ventilation System
: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Ethyl Chloroacetate is a clear liquid.
Odor: It has pungent & fruity odor
Solubility: It is insoluble in water.
pH: NA
Density: 1.1498 g/mL at 25C
Molecular Formula
: ClCH2CO2C2H5
Molecular Weight: 122.55
% Volatile by volume @ 21C (70F): -
Boiling Point: 142-145░C
Melting Point: NA
Vapor Density (Air=1): 4.3.
Vapor Pressure (mm Hg): 4.87mmHg @ 25C.
Evaporation Rate (BuAc=1): No information found.

10. Stability and Reactivity

Stability: Ethyl Chloroacetate is stable under ordinary conditions of use and storage. Slow hydrolysis to ethanol and chloroacetic acid will cause slow corrosion of common metals.
Hazardous Decomposition Products: It emits Carbon dioxide, Carbon monoxide Ethyl alcohol, Hydrochloric acid & Fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, strong reducing agents, strong acids, strong bases.
Conditions to Avoid: Incompatibles, oxidizing agents, strong alkalis, strong acids, heat & light.

11. Toxicological Information

Harmful if inhaled or swallowed. Irritating to eyes & skin.

Toxicity data
ORL-RAT LD50 180 mg kg-1
ORL-MAM LD50 350 mg kg-1
Dermal Rabbit LD50 230 mg/kg

Carcinogenicity: CAS# 105-39-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found

12. Ecological Information

Environmental Toxicity:
Toxicity to fish: LC50 - Danio rerio (zebra fish) - 1,48 mg/l - 96,0 h
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 1,6 mg/l - 48 h

Environmental Fate: Not available.
BOD5 and COD: Not available. The product is expected to have high BOD.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely.
Toxicity of the Products of Biodegradation: NA.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

US DOT Classification:
Shipping Name: ETHYL CHLOROACETATE
Hazard Class: 6.1(3)
UN Number: UN1181
Packing Group: II

Canada TDG Classification:
Shipping Name: ETHYL CHLOROACETATE
Hazard Class: 6.1(3)
UN Number: UN1181
Packing Group: II

IATA & ADR/RID
Shipping Name: ETHYL CHLOROACETATE
Hazard Class: 6.1(3)
UN Number: UN1181
Packing Group: II

15. Regulatory Information

USA:
TSCA
: CAS# 105-39-5 is listed on the TSCA Inventory.
SARA 302 Components: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components: No chemicals are reportable under Section 313.
SARA 311/312 Hazards: Fire Hazard: Yes, Reactivity Hazard: -, Pressure Hazard: -, Immediate Health Hazard: Acute Yes, Chronic Health Hazard: -
Massachusetts Right To Know Components : Listed
Pennsylvania Right To Know Components: Listed
New Jersey Right To Know Components: Listed
California prop. 65:: Contains no chemical subject to California Prop 65.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.

EINECS EC No.: 203-294-0
Hazard Symbols: TN
Risk Phrases:
R 10 Flammable.
R 23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R 50 Very toxic to aquatic organisms.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
S 7/9 Keep container tightly closed and in a well-ventilated place.
S 61 Avoid release to the environment.

WGK (Water Danger/Protection)
CAS# 105-39-5: 2

Canada - DSL/NDSL : CAS# 105-39-5: is listed on Canada's DSL List.
Canada - WHMIS: CLASS B3, D1A, D2B.
Canadian Ingredient Disclosure List: CAS# 105-39-5 is listed on Canada's Ingredient Disclosure List.
Canadian Domestic Substance List (DSL) Inventory Listing
Listed on the DSL.

16. Other Information

H226 =Flammable liquid and vapor.
H301 =Toxic if swallowed.
H311 =Toxic in contact with skin.
H318 = Causes serious eye damage.
H331 = Toxic if inhaled.
H400 = Very toxic to aquatic life.

Hazard symbol(s):
T = Toxic
N = Dangerous for the environment
R-phrase(s):
R 10 Flammable.
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R50 Very toxic to aquatic organisms.

Disclaimer:
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Our company provides this Ethyl Chloroacetate SDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This Ethyl Chloroacetate MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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Ethyl Chloroacetate manufacturers

Anmol Chemicals
S-8, SARIFA MANSION, 2ND FLANK ROAD, CHINCHBUNDER, MUMBAI 400009, INDIA
TEL: (OFFICE) 91-22-23770100, 23726950, 23774610, 23723564. FAX: 91-22-23728264

e-mail: anmolc@mtnl.net.in

Anmol Chemicals

Alpha Beta Gamma methyl ionone -- Benzyl acetate -- Benzyl benzoate -- Benzyl salicylate -- BHA Butylated hydroxyanisole & BHT Butylated hydroxytoluene -- Cinnamaldehyde Cinnamic aldehyde -- Ethyl naphthyl ether or Nerolin bromelia -- Ethyl chloroacetate -- HEDP Hhydroxyethylidenediphosphonic acid -- Isatoic anhydride -- Maleic acid -- Manzanate; Ethyl 2 Methyl Pentanoate or Valerate -- Methyl salicylate -- Phenyl ethyl propionate Phenyl ethyl acetate -- Sodium formaldehyde bisulfite -- TBHQ Tert or Tertiary butylhydroquinone -- Dimethyl anthranilate -- Geranyl nitrile -- Styrallyl acetate -- Sodium salicylate

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